production of yttrium aluminum silicate microspheres by gelation of an aqueous solution containing yttrium and aluminum ions in silicone oil

Production of yttrium aluminum silicate microspheres by gelation of an aqueous solution containing yttrium and aluminum ions in silicone oil

Background: Radioactive yttrium glass microspheres are used for liver cancer treatment. These yttrium aluminum silicate microspheres are synthesized from yttrium, aluminum and silicone oxides by melting. There are two known processes used to transform irregular shaped glass particles into microspheres, these ‘spheroidization by flame’ and ‘spheroidization by gravitational fall...

Yttrium Aluminum Garnet Laser Materials

Yttrium Aluminum Garnet Fibers from Metalloorganic Precursors

Mixtures of yttrium acetate hydrate (Y(O2CCH3)3?4H2O) and aluminum formate hydrate (Al(O2CH)3?3H2O in H2O) or yttrium isobutyrate (Y[O2CCH(CH3)2]3) and aluminum isobutyrate (Al[O2CCH(CH3)2]3) in tetrahydrofuran were used as precursors to process yttrium aluminum garnet (YAG, Al5Y3O12) fibers. The pyrolytic decomposition patterns of Al(O2CH)3?3H2O, Y(O2CCH3)3?4H2O, and a [3Y(O2CCH3)3?4H2O/5Al(O2...

Interactions of silicate ions with zinc(II) and aluminum(III) in alkaline aqueous solution.

We present (29)Si, (27)Al, and (67)Zn NMR evidence to show that silicate ions in alkaline solution form complexes with zinc(II) (present as zincate, Zn(OH)(3)(-) or Zn(OH)(4)(2-)) and, concomitantly, with aluminate (Al(OH)(4)(-)). Zincate reacts with monomeric silicate at pH 14-15 to form [(HO)O(2)Si-O-Zn(OH)(3)](4-) and with dimeric silicate to produce [HO-SiO(2)-O-SiO(2)-O-Zn(OH)(3)](6-). The...

Fluoride Ions Removal using Yttrium Alginate Biocomposite from an Aqueous Solution (RESEARCH NOTE)

Removal of fluoride ions was investigated using a new adsorbent of yttrium alginate biocomposite (YALG). Effect of various parameters such as pH, contact time, initial concentration of fluoride ions and temperature on the sorption capacity of adsorbent was studied. Performing a mathematical assessment of fluoride sorption, isotherm and kinetics models including Freundlich & Langmuir isotherms a...

Three-photon absorption in Nd-doped yttrium aluminum garnet

This paper presents the results of a study of resonantly enhanced, three-, photon absorption in Nd-doped yttrium aluminum garnet (Y3Alg0~2) or Nd: YAG. The trivalent ions of the rare-earth elements, such as Nd'+, are characterized by energy levels which remain relatively sharp even in a crystalline environment, and thus crystalline solids doped with rare-earth ions present interesting systems i...